Reduction of the transition temperatures in mesomorphic lanthanide complexes by the exchange of counter-ions

1 January 1998

journal article
Published by Royal Society of Chemistry (RSC) in Journal of Materials Chemistry

Vol. 8 (7) , 1551-1553
https://doi.org/10.1039/a803227k

Abstract

Metathesis of the chloride anion in the mesomorphic lanthanide complexes [LnL(LH)₂ ][Cl]₂ (LH=salicylaldimine; Ln=lanthanide element) by dodecyl sulfate (DOS) leads to the complexes [LnL(LH)₂ ][DOS]₂ , which have wider mesomorphic ranges and lower clearing points.

Keywords

TRANSITION
MESOMORPHIC
LANTHANIDE
SALICYLALDIMINE
ANION
WIDER
CHLORIDE
METATHESIS
DODECYL

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