[ClZn8(SPh)16]–, A new, highly symmetrical cage containing metal atoms inside and outside an icosahedron of ligands; X-ray crystallographic study

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Abstract
In the molecular cage [ClZn4(µ-SPh)12(ZnSPH)4]– the central chlorine atom is surrounded by a tetrahedron of zinc atoms, which is enclosed by an icosahedron of bridging benzenethiolate ligands, which links to an outer tetrahedral array of ZnSPh groups; the symmetry of the complete cage, excluding only the four outer phenyl-groups, is very close to that of the cubic point group T.