Chiral Tricarbonyl(η6Arene)Chromium(0) Complexes in Stereoselective Hetero Diels-Alder Reactions

Abstract
Zinc chloride promoted stereoselective cyclocondensation of the Danishefsky diene to ortho-substituted benzaldehyde and benzaldimine chromium tricarbonyl complexes gave 2,3-dihydro-4-pyridinone and 2,3-dihydro-4-pyranone derivatives in fairly good yields and with complete stereoselection.

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