Oxidation of primary aromatic amines to nitro derivatives catalysed by iron(III) and manganese(III) tetraaryl porphyrins

1 January 1993

journal article
research article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications

No. 5,p. 442-444
https://doi.org/10.1039/c39930000442

Abstract

The oxidation of primary aromatic amines to the corresponding nitro derivatives has been observed in catalytic systems (turnovers/hour up to 18000) containing tert-butyl hydroperoxide and metallo-tetraaryl porphyrins (metal = Fe^III or Mn^III) in the presence of heterocyclic nitrogen bases acting as axial ligands.

Keywords

NITROGEN
PRIMARY AROMATIC
AROMATIC AMINES
III
CORRESPONDING
TURNOVERS/HOUR
AXIAL

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