Application of ion imaging to the atom–molecule exchange reaction: H+HI→H2+I
- 15 March 1991
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 94 (6) , 4672-4675
- https://doi.org/10.1063/1.460598
Abstract
The bimolecular abstraction reaction H+HI→H2+I has been investigated in a neat molecular beam of HI using ion imaging to detect the H2 (v=1,J=11,13) products. Images obtained determine the laboratory‐frame product velocity distribution and show evidence for reaction with fast and slow H atoms arising from the I (2P3/2) and I*(2P1/2) channels in the photolysis of HI, as well as formation of I and I* in the reaction product channel.Keywords
This publication has 22 references indexed in Scilit:
- Photodissociation of acetylene: Determination of D00 (HCC–H) by photofragment imagingThe Journal of Chemical Physics, 1990
- Effect of indistinguishable nuclei on product rotational distributions: D+DI→D2+IChemical Physics Letters, 1990
- Photofragment imaging: the 266-nm photolysis of CD3IThe Journal of Physical Chemistry, 1990
- A new method for the treatment of reactive collisions involving one light and two heavy nucleiChemical Physics Letters, 1989
- State‐to‐state dynamics of H+HX collisions. I. The H+HX→H2+X (X=Cl,Br,I) abstraction reactions at 1.6 eV collision energyThe Journal of Chemical Physics, 1989
- Photofragment imaging: The 266 nm photodissociation of CH3IChemical Physics Letters, 1989
- The H+D2 reaction: “prompt” hd distributions at high collision energiesChemical Physics Letters, 1988
- Theory of electronic branching in the photodissociation of HI and DIThe Journal of Chemical Physics, 1988
- Potential-energy curves for molecular hydrogen and its ionsAtomic Data and Nuclear Data Tables, 1970
- Production of electronically excited atoms. II. H + HI->H2 + I*(2P1/2)The Journal of Physical Chemistry, 1968