3αβ-Hydroxy-7αβ-methylperhydroinden-4-one Derivatives en route to Analogues of Cardenolides
- 1 July 1997
- journal article
- letter
- Published by Georg Thieme Verlag KG in Synlett
- Vol. 1997 (7) , 833-835
- https://doi.org/10.1055/s-1997-5766
Abstract
3αβ-Hydroxy-7αβ-methylperhydroinden-4-one derivative 2 was efficiently transformed into allylic chloride 11 which served as the electrophilic partner for Pd-catalysed cross-coupling reactions yielding 14β-hydroxy-9,10-secosteroids 1.Keywords
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