Silylated Phosphines and Phosphoranimines
- 1 March 1987
- journal article
- research article
- Published by Taylor & Francis in Phosphorus and Sulfur and the Related Elements
- Vol. 30 (1) , 463-466
- https://doi.org/10.1080/03086648708080620
Abstract
The N-silyl phosphoranimines [e.g., Me3SiN=P(OCH2CF3)Me2] undergo a variety of reactions including deprotonation/substitution of the P-Me groups, transilylation, and condensation with reactive phosphines. Some new 1,2-addition and oxidation reactions of the P=C systems, R2NP=CHR, R2NP(=NR)=CHR, and R2NP=CR-CH=CHR (R = SiMe3) are also reported.Keywords
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