STRUCTURAL STUDY OF POLY(CARBON DISELENIDE)
- 5 January 1985
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 14 (1) , 1-4
- https://doi.org/10.1246/cl.1985.1
Abstract
Poly(carbon diselenide) is metallic in an ordered crystalline state and it becomes less conductive when crystalline imperfection increases. EXAFS spectra show the existence of Se–Se bonds and the co-ordination number of Se in metallic poly(carbon diselenide) is almost 2.0, indicating the infinite chains of Se atoms. Extended Huckel calculation gave a reasonable interpretation of the metallic nature of crystalline poly(carbon diselenide).Keywords
This publication has 1 reference indexed in Scilit:
- The electronic structure of Fe1+xNb3-xSe10Solid State Communications, 1982