Resonance Energies of Benzene and Butadiene
- 1 July 1953
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 21 (7) , 1249-1254
- https://doi.org/10.1063/1.1699176
Abstract
The resonance energy of benzene based on an ethane‐ethylene‐like Kekulé structure is 74.86 kcal. The similar quantity for butadiene is 17.28 kcal. These quantities are independent of the value of the heat of sublimation of carbon. They are obtained from the heats of atomization of the appropriate molecules or from the heats of hydrogenation of the pertinent related compounds. Both methods yield the same results if properly applied.Keywords
This publication has 3 references indexed in Scilit:
- Bond Energies and Bond Distances of HydrocarbonsThe Journal of Chemical Physics, 1953
- LCAO Molecular Orbital Computation of Resonance Energies of Benzene and Butadiene, with General Analysis of Theoretical Versus Thermochemical Resonance EnergiesThe Journal of Chemical Physics, 1951
- Heats of Organic Reactions III. Hydrogenation of Some Higher OlefinsJournal of the American Chemical Society, 1936