Large negative cubic hyperpolarizability for the spin-crossover compound cis-bis(thiocyanato)bis[N-(2-pyridylmethylene)aminobiph enyl]iron(ii)
- 1 January 1997
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 8,p. 745-746
- https://doi.org/10.1039/a700019g
Abstract
The first example of a spin-crossover iron(II) compound with a large negative third-order polarizability, associated with an instantaneous electronic response, is reported; magnetic measurements show that this compound, cis-bis(thio-cyanato)bis[N-(2-pyridylmethylene)aminobip henyl]iron(II), characterized by X-ray structural data is in the high-spin form at room temperature.Keywords
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