Studies in germyl chemistry. Part VI. Digermylcarbodi-imide
- 1 January 1968
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 1423-1426
- https://doi.org/10.1039/j19680001423
Abstract
Digermylcarbodi-imide has been obtained from germyl fluoride and bis(trimethylsilyl)carbodi-imide; the vibrational spectra indicate that the compound is a carbodi-imide rather than a cyanamide. The selection rules are consistent with a linear heavy-atom skeleton, but the absence of resolved rotational detail implies that the skeleton is bent. The compound is a useful synthetic intermediate in the preparation of other germyl derivatives.Keywords
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