Crystal and molecular structure of tri-µ-chloro-pentacarbonyl(trichlorostannyl)diruthenium
- 1 January 1970
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc. A
- p. 245-248
- https://doi.org/10.1039/j19700000245
Abstract
The structure of tri-µ-chloro-pentacarbonyl(trichlorostannyl)diruthenium, (SnCl3)Ru2Cl3(CO)5, has been determined by X-ray single-crystal methods. The final R for 886 observations collected by counter methods, is 6·4%. The crystals are monoclinic, space group P21/n with a= 10·414, b= 11·164, c= 14·674 Å, and β= 96° 43′. Both ruthenium atoms have distorted octahedral configuration. The two octahedra share a common face defined by three chlorine atoms; the mean Ru–Cl distances being 2·43 Å. The Ru ⋯ Ru distance is 3·157 Å.Keywords
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