Dehydrogenation of 7,12-Dihydropleiadene Compounds with High Potential Quinones
- 1 June 1971
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 49 (11) , 1848-1860
- https://doi.org/10.1139/v71-303
Abstract
Dehydrogenation with high potential quinones has been extended to dihydro derivatives of non-aromatic hydrocarbons using 7,12-dihydropleiadenes as models. Reaction of 7-phenyl-7,12-dihydropleiadene with high potential quinones resulted in dehydrogenative cyclization whereas preparative scale and rate studies in 9-aryl-9,10-dihydroanthracenes gave no evidence of aryl participation during quinone dehydrogenation due to geometrical restrictions on this system.Keywords
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