Kristallstruktur von Na4OBr2 / Crystal Structure of Na4OBr2

Abstract
The colourless compound Na4OBr2 has been prepared and its crystal structure determined by X-ray diffraction. Very hygroscopic Na4OBr2 crystallizes in the tetragonal space group I 4/mmm (Z = 2) with the cell parameters a = 452.1(3) and c = 1490.8(1) pm. The structure was solved from 267 symmetry independent reflections by Patterson and Fourier methods (R = 0.028; wR = 0.029). Na4OBr2 crystallizes in the anti-K2NiF4-structure type and is isotypic to Na4OI2 and K4OBr2 which have been described earlier.

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