Synthesis and characterization of the binuclear complex di-µ-oxo-bis[N,N′-bis(2-methylpyridyl)ethane-1,2-diamine]dimanganese(III,IV)perchlorate trihydrate,[(bispicen)MnO]₂(ClO₄)₃·3H₂O

1 January 1987

journal article
Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications

No. 21,p. 1659-1660
https://doi.org/10.1039/c39870001659

Abstract

The title complex, a new binuclear di-µ-oxo complex of manganese-(III) and -(IV) with a single tetradentate ligand in place of the previously reported bidentate bpy or phen ligands, has been synthesised and characterised by X-ray crystallography and cyclic voltammetry.

Keywords

BINUCLEAR
OXO
BISPICEN
METHYLPYRIDYL
CLO
CHARACTERISED

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Synthesis and characterization of the binuclear complex di-µ-oxo-bis[N,N′-bis(2-methylpyridyl)ethane-1,2-diamine]dimanganese(III,IV)perchlorate trihydrate,[(bispicen)MnO]2(ClO4)3·3H2O

Abstract

Keywords

Synthesis and characterization of the binuclear complex di-µ-oxo-bis[N,N′-bis(2-methylpyridyl)ethane-1,2-diamine]dimanganese(III,IV)perchlorate trihydrate,[(bispicen)MnO]₂(ClO₄)₃·3H₂O