Organoimido complexes of tungsten(IV) containing π-alkene and π-acetylene ligands. The X-ray crystal structure of dichloro(diphenylacetylene)phenylimidobis(trimethylphosphine)tungsten(IV), [WCl2(NPh)(PhCCPh)(PMe3)2]
- 1 January 1989
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 6,p. 343-345
- https://doi.org/10.1039/c39890000343
Abstract
Reduction of [WCl3(NPh)(PMe3)2)] under ethylene or propene leads to the complexes [WCl2(NPh)(π-alkene)(PMe3)2], and reaction of [WCl2(NPh)(PMe3)3] with a variety of acetylenes gives [WCl2(NPh)(π-acetylene)(PMe3)2]; the structure of [WCl2(NPh)(PhCCPh)(PMe3)2] has been established by X-ray crystallography.Keywords
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