Three-body S-state wavefunctions: symmetry and degrees of freedom associated with normalisation of the exact wavefunction
- 11 July 1985
- journal article
- research article
- Published by IOP Publishing in Journal of Physics A: General Physics
- Vol. 18 (10) , 1687-1696
- https://doi.org/10.1088/0305-4470/18/10/023
Abstract
The few-particle Schrodinger equation does not define the symmetry of the wavefunction, which must be chosen to match the symmetry of the particles. It is shown, by reference to the S-states of a three-particle system, that the symmetry does constrain degrees of freedom associated with normalisation of the exact wavefunction. The first particle is treated as infinitely massive, and distinguishable. The systems where the second and third particles are (i) distinguishable, (ii) indistinguishable with a symmetric wavefunction (bosons) and (iii) indistinguishable with an antisymmetric wavefunction (fermions) may be treated as special cases of a continuous description of particle symmetry. Cases (ii) and (iii) are opposite extremes in the analysis.Keywords
This publication has 9 references indexed in Scilit:
- On exact analytical solutions for the few-particle Schrodinger equation. IV. The asymptotic form and normalisability of the wavefunctionJournal of Physics A: General Physics, 1983
- On exact analytical solutions for the few-particle Schrodinger equation. III. Spatially symmetric S states of two identical particles in the field of a massive third particleJournal of Physics A: General Physics, 1983
- Exact solution of coupled equations and the hyperspherical formalism: Calculation of expectation values and wavefunctions of three Coulomb-bound particlesAnnals of Physics, 1983
- On exact analytical solutions for the few-particle Schrödinger equation. II. The ground state of heliumProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1982
- On exact analytical solutions for the few-particle Schrödinger equation. I. A perturbation studyProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1982
- The validity of Kinoshita's expansion for S-state eigenfunctions of the helium atomJournal of Physics A: General Physics, 1978
- Formal solution for the three body problem in helium theoretical chemistryTheoretical Chemistry Accounts, 1973
- Analytic Approach to Electron Correlation in AtomsThe Journal of Chemical Physics, 1970
- Neue Berechnung der Energie des Heliums im Grundzustande, sowie des tiefsten Terms von Ortho-HeliumThe European Physical Journal A, 1929