A Relation between Internuclear Distances and Potential Barriers of Methyl Groups
- 1 June 1946
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 14 (6) , 389-394
- https://doi.org/10.1063/1.1724157
Abstract
An empirical relation is shown between contributions of various groups to the potential barriers of methyl groups and the minimum distance of approach of atoms of these groups to the methyl group. The use of this relation to derive barrier values for other molecules is demonstrated.Keywords
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