Novel layered sulfides of tin: synthesis and structural characterization of Cs4Sn5S12·2H2O and Sn5S12(N2C4H11)2(N4C10H24)
- 1 January 1994
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 1,p. 69-70
- https://doi.org/10.1039/c39940000069
Abstract
Framework compositions [Sn5S12]4– have been synthesized hydrothermally in the presence of triethylenediamine (Dabco) and caesium, respectively; the cations are accommodated between the sheets with orientation relationships suggestive of a templating mechanism and their crystal structures have been determined.Keywords
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