The role of the ‘glow phenomenon’ in the preparation of sulfated zirconia catalysts

Abstract
During the calcination procedure that is necessary to obtain sulfated zirconia catalysts from hydroxide precursors an exothermic reaction occurs in the heat-up period which can lead to a rapid overheating (‘glow’) of the sample bed; the batch size is identified as a critical parameter that influences heat transfer and thus the extent of the temperature overshoot and the catalytic activity of the product.

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