Abstract
The gas-phase heats of formation of the following are reported; dimethyl, diethyl, methyl ethyl, d-n-propyl and di-n-butyl sulphites; dimethyl, diethyl, di-n-propyl and di-n-butyl sulphates. These have been evaluated via their heats of combustion and vaporization. The mean dissociation energies of the S—O single bonds have been derived.

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