Potential-Correlation Function Duality in Statistical Mechanics

Abstract
The Feynman path‐integral formulation is used to analyze the grand‐partition function Z and the n‐body Green's function Gn or rather their cumulants (or connected parts) n for a system governed by p‐body interaction potentials vp. It is shown that the functional relationship expressing n in terms of vp is invariant under the transformation exchanging −(−)mm and vm everywhere. Under the same transformation log Z undergoes a change of sign. The content of these results is discussed in conclusion.

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