Further polyacetylenes from Polyporus anthracophilus: specific incorporation of [1-14C]matricaria esters into polyacetylenic metabolites of this fungus
- 1 January 1978
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 12,p. 1602-1606
- https://doi.org/10.1039/p19780001602
Abstract
A further eight C10 polyacetylenes have been isolated from cultures of Polyporus anthracophilus. Several of these, notably Z,Z- and 2E,8Z-matricaria ester and Z,Z-matricarianol, have not previously been isolated from fungi. When a mixture of E,E-[1-14C]matricaria ester and 2E,8Z-[1-14C]matricaria ester was fed to cultures of P. anthracophilus, one or both of these esters were specifically incorporated into E,E-matricarianol, Z,Z-matricarianol, and dimethyl E,E-deca-2,8-diene-4,6-diyne-1,10-dioate. This provides strong evidence that in this organism, matricaria esters are intermediates in the production of many of the polyacetylenic metabolites.This publication has 1 reference indexed in Scilit:
- The Synthesis of Triazole Analogs of Histamine and Related CompoundsJournal of the American Chemical Society, 1949