Statistical thermodynamics foundation for photovoltaic and photothermal conversion. II. Application to photovoltaic conversion

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Abstract
The general theory developed in part I was applied to build up two models of photovoltaic conversion. To this end two different systems were analyzed. The first system consists of the whole absorber (converter), for which the balance equations for energy and entropy are written and then used to derive an upper bound for solar energy conversion. The second system covers a part of the absorber (converter), namely the valence and conduction electronic bands. The balance of energy is used in this case to derive, under additional assumptions, another upper limit for the conversion efficiency. This second system deals with the real location where the power is generated. Both models take into consideration the radiation polarization and reflection, and the effects of concentration. The second model yields a more accurate upper bound for the conversion efficiency. A generalized solar cell equation is derived. It is proved that other previous theories are particular cases of the present more general formalism.

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