On the origin of 1,5-induction in tin(IV) halide-promoted reactions of 4-alkoxyalk-2-enylstannanes with aldehydes
- 1 January 1998
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 8,p. 899-900
- https://doi.org/10.1039/a800781k
Abstract
A combination of experiment and theory has identified both the allyltin trichlorides 3 (R2 = Bn, H) as key intermediates in tin(IV) chloride-promoted reactions of allylstannanes 1 (R2 = Bn, H) and the transition structures that are involved in their reactions with aldehydes.Keywords
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