A NEW CONVERSION OF SILYL ENOL ETHERS INTO THE CORRESPONDING BORON ENOLATES WITH DIALKYLBORON HALIDES OR DIALKYLBORON TRIFLATES, AND CROSS ALDOL REACTIONS VIA THE BORON ENOLATES
- 5 February 1981
- journal article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 10 (2) , 153-156
- https://doi.org/10.1246/cl.1981.153
Abstract
Silyl enol ethers react with dialkylboron halides or dialkylboron triflates to give the corresponding boron enolates quantitatively under mild conditions. Boron enolates thus generated are effectively used to afford cross aldol products with benzaldehyde.This publication has 2 references indexed in Scilit:
- Regio- and Stereoselective Cross-aldol Reactions via Dialkylboryl TriflatesBulletin of the Chemical Society of Japan, 1980
- Stereoselective aldol condensations via boron enolatesJournal of the American Chemical Society, 1979