Ditertiary phosphine rhodium and iridium complexes containing the molecular unit S2 or Se2 as a ligand
- 1 January 1971
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society D: Chemical Communications
- No. 5,p. 232-233
- https://doi.org/10.1039/c29710000232
Abstract
Cyclo-octasulphur and cyclo-octaselenium react with [Ir(dppe)2]Cl and [Rh(dmpe)2]Cl (dppe = Ph2P·CH2·CH2·PPh2 and dmpe = Me2P·CH2·CH2·PMe2) to form the complexes [Ir(S2)(dppe)2]Cl (1), [Ir(Se2)(dppe)2]Cl (2), and [Rh(S2)(dmpe)2]Cl (3).Keywords
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