Assignment of13C-NMR Spectra of Grayanotoxin-I and -III

Abstract
As the first step towards the biosynthetic studies on grayanotoxins with the aid of 13C isotope, the 13C-NMR spectra of grayanotoxin-I and -III were assigned. Unambiguous assignments were achieved except for the C–9 and C–13 resonances in G-I by selective proton decoupling technique as well as by comparison with chemical shift values of the related compounds.

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