Ligand-field photolysis of the fischer complex, (OC)5WC(OMe)Ph: time-resolved resonance Raman spectroscopic evidence for alkyl–metal interaction following co photodissociation
- 1 January 1986
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 24,p. 1785-1787
- https://doi.org/10.1039/c39860001785
Abstract
Transient resonance Raman spectroscopy suggests that the co-ordinatively unsaturated fragment produced by ligand field photodissociation of the Fischer complex, (OC)5WC(OMe)Ph, undergoes rapid (<10 ns) rearrangement to a species displaying a partial bonding interaction between the methyl group and the metal centre.Keywords
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