Novel dinuclear iridium(I) and mixed iridium(I)-rhodium(I) complexes. X-Ray crystal structure of di-µ-benzenethiolato-bis[dicarbonyliridium(I)]
- 1 January 1977
- journal article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 2,p. 47b-49
- https://doi.org/10.1039/c3977000047b
Abstract
The thiolato-bridged iridium(I) carbonyl complexes [{Ir(SR)(CO)2}2](R = But or Ph) have been prepared by the reaction of [{Ir(SR)(C8H12)}2] in pentane with CO, and the crystal structure of [{Ir(SPh)(CO)2}2] suggests the existence of intra- and inter-molecular metal–metal interactions; similar mixed iridium(I)–rhodium(I) chloro-bridged complexes have also been prepared.Keywords
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