Polycyclic fluoro-aromatic compounds. Part 7. Nucleophilic replacement in decafluoropyrene
- 1 January 1979
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- p. 1351-1353
- https://doi.org/10.1039/p19790001351
Abstract
Decafluoropyrene reacts with sodium methoxide with replacement of the fluorine atom at position 1, and then those at 3, 6, and 8. This has been proved by n.m.r. spectroscopy and by chemical means, and is rationalized by a recently published modification of the Iπ repulsion theory.Keywords
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