Heterolytic C–O cleavage in arylethers activated by [Fe(η5-C5H5)]+
- 1 January 1995
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 4,p. 463-464
- https://doi.org/10.1039/c39950000463
Abstract
The C–O bond of Fe(η5-C5H5)+ complexes of aryl ethers is cleaved smoothly by reaction of ButOK in THF or KOH in DME, yielding π-phenate complexes; transetherification can also be achieved in situ at room temperature.Keywords
This publication has 14 references indexed in Scilit:
- The Base-Catalyzed H/D-Exchange of Anisole Moiety of Ruthenium Complex in Cooperation with Demethylation by Hydroxide Anion in Methanol-d4Bulletin of the Chemical Society of Japan, 1992
- The use of π-organoiron sandwiches in aromatic chemistryPublished by Springer Nature ,1992
- Bis(phenol) adduct of Cp*Ru(.eta.5-oxocyclohexadienyl), a doubly symmetrical hydrogen-bridged ruthenium complexOrganometallics, 1991
- Stabilization of the dienonylic form of the A-ring of .beta.-estradiol by the "Cp*Rh" fragment. X-ray structure of the rhodium complex .alpha.-[(.eta.5-estradienonyl)RhCp*]BF4 (Cp* = C5Me5)Organometallics, 1990
- Alkoxy and aryloxy derivatives of (pentamethylcyclopentadienyl)ruthenium. X-ray crystal structures of [(.eta.5-C5Me5)Ru(.mu.-OMe)]2, [(.eta.5-C5Me5)(CO)Ru(.mu.-OEt)]2, and (.eta.5-C5Me5)Ru(.eta.5-2,6-tBu2C6H3O) and molecular orbital analysis of [(.eta.5-C5H5)Ru(.mu.-OMe)]2Journal of the American Chemical Society, 1989
- Selective preparation of unusual π-adducts of the functional arenes diphenylacetylene, phenol, and benzoic acid with the CpRu+fragment (Cp = C5Me5)Journal of the Chemical Society, Chemical Communications, 1989
- Reactions of cyclopropenyl cations with Group VIB metal carbonyl anions. Synthesis of .eta.3-oxocyclobutenyl complexes of chromium, molybdenum, and tungstenOrganometallics, 1985
- Synthesis and deprotonation of η6-arene-η5-cyclopentadienyliron(II) complexes Bearing NH2OH OR SH substituentsJournal of Organometallic Chemistry, 1979
- Nucleophilic addition to organotransition metal cations containing unsaturated hydrocarbon ligandsTetrahedron, 1978
- π-Arene and π-phenoxo complexes of ruthenium and rhodiumJ. Chem. Soc., Dalton Trans., 1976