Effects of structural changes on chiral selectivity in molecular complexation
- 1 January 1975
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 11,p. 444-446
- https://doi.org/10.1039/c39750000444
Abstract
Seven macrocyclic ethers containing 2,2′-substituted-1,1′-binaphthyl units as chiral barriers connected through different combinations of OCH2CH2OCH2-CH2O, O[CH2]5O, m-C6H4(CH2O)2 and 2,6-C5H3N(CH2O)2(substituted pyridyl) units complex differently with the enantiomers of the hexafluorophosphate salts of racemic methyl phenylglycinate and methyl valinate.Keywords
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