Coulombic Criticality in General Dimensions
- 14 November 1994
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review Letters
- Vol. 73 (20) , 2716-2719
- https://doi.org/10.1103/physrevlett.73.2716
Abstract
Debye-Hückel theory for spheres of diameter with charges is extended to general dimension . Explicit results include Bjerrum association of +/- ions and the dipole-ionic solvation energy. For all a critical point terminates conducting-liquid-conducting-vapor coexistence: The critical density falls with , but rises. When , an insulating vapor appears for (the Kosterlitz-Thouless point), separated from conducting fluid by an infinite-order critical line ending at a tricritical point: , the transition is first order.
Keywords
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