Molecular precursors of bismuth oxide. Synthesis and structure of [Bi2(µ2-OC2H4OMe)4(OC2H4OMe)2]∞, a one-dimensional ribbon-like chain
- 1 January 1990
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 4,p. 301-302
- https://doi.org/10.1039/c39900000301
Abstract
Compounds [Bi(OBut)3]∞ and [Bi2(µ2-OC2H4OMe)4(OC2H4OMe)2]∞ have been obtained by metathesis reactions between bismuth halides and the appropriate alkali alkoxides; X-ray structure analysis shows a one-dimensional extended ‘skew’ chain structure based on dimeric asymmetric Bi2(OC2H4OMe)6 units in which the metal displays a pyramidal tetragonal surrounding, with a small number of additional neighbours.Keywords
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