Abstract
High-yield syntheses of two new types of dppm (PH2PCH2PPh2) complexes are described: (i) the fluxional complexes trans-[Pt(CCR)2(η1-dppm)2], and (ii) the ‘face-to-face’ binuclear complexes [Pt2(CCR)42-dppm)2](R = Ph or p-tolyl).

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