Reactions and Utilizations of Higher Alkylene Oxides

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Abstract
Reactions and utilizations of higher alkylene oxides were investigated. The used oxides were 1, 2-epoxyoctane, 1, 2-epoxydecane and 1, 2-epoxydodecane synthesized from corresponding α-olefins by using peracetic acid. These oxides reacted easily with some organic acids, hydroxy compounds and amino compounds as compounds having active hydrogen. Higher alkylene oxides reacted also with benzene in the presence of aluminium chloride and could be polymerized in the presence of the same catalysts that had been used for the polymerizations of lower alkylene oxides. Furthermore, utilizations of the products in the reactions of oxides with some compounds having active hydrogen were investigated.

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