Corrections to the Fuoss–Onsager Theory of Electrolytes
- 15 September 1970
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 53 (6) , 2173-2186
- https://doi.org/10.1063/1.1674311
Abstract
Mathematical corrections are made to the theory of Fuoss and Onsager for the conductivity of ionic solutions to first order in the concentration. The theory is extended to cover the case of asymmetric binary electrolytes; it is found that in this case the results are strongly affected by deviations of the equilibrium ion pair distribution function from that predicted by the Debye–Hückel theory. The results of the conductivity theory are compared to corresponding results of the equilibrium theory.Keywords
This publication has 13 references indexed in Scilit:
- The Conductance of Symmetrical Electrolytes. V. The Conductance Equation1,2The Journal of Physical Chemistry, 1965
- The Conductance of Symmetrical Electrolytes.1a IV. Hydrodynamic and Osmotic Terms in the Relaxation FieldThe Journal of Physical Chemistry, 1964
- THE CONDUCTANCE OF SYMMETRICAL ELECTROLYTES. II. THE RELAXATION FIELDThe Journal of Physical Chemistry, 1963
- THE CONDUCTANCE OF SYMMETRICAL ELECTROLYTES. I. POTENTIAL OF TOTAL FORCEThe Journal of Physical Chemistry, 1962
- Conductance of Unassociated Electrolytes.The Journal of Physical Chemistry, 1957
- CONDUCTANCE OF STRONG ELECTROLYTES AT FINITE DILUTIONSProceedings of the National Academy of Sciences, 1955
- The Activity Coefficients of LaCl3, CaCl2, KCl, NaCl and HCl in Dilute Aqueous SolutionsJournal of the American Chemical Society, 1950
- The Electrolytic Conductivity of Alkaline Earth Chlorides in Water at 25°Journal of the American Chemical Society, 1934
- The Conductance of Aqueous Solutions as a Function of the Concentration. I. Potassium Bromide and Lanthanum ChlorideJournal of the American Chemical Society, 1934
- The Conductance of Aqueous ElectrolytesTransactions of The Electrochemical Society, 1934