Product characterization in the thermal bond-relocation of the syn- and anti-9-methylbicyclo[6,1,0]nona-2,4,6-trienes
- 1 January 1972
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 7,p. 399-400
- https://doi.org/10.1039/c39720000399
Abstract
anti-9-Methylbicyclo[6,1,0]nona-2,4,6-triene thermolyses overwhelmingly to a cis-8,9-dihydroindene skeleton while under similar conditions the syn-counterpart generates a mixture consisting of ca. 70%cis-fused and 30%trans-fused 8,9-dihydroindenes.Keywords
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