On pentavalent perfluoroorgano bismuth compounds
- 1 November 1989
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 67 (11) , 1949-1951
- https://doi.org/10.1139/v89-303
Abstract
The reactions of Bi(Rf)3 (Rf = CF3, C6F5) with a series of oxidizing halogenation reagents have been investigated. From the reactions of Bi(Rf)3 with Cl2, Br2, I2, ICl, and IF5 no oxidation to Bi(V) compounds can be detected; in all cases the Bi(III) halides and the corresponding RfX compounds are formed. Only the reaction of Bi(C6F5)3 with XeF2 yields the perfluoroorganobismuth(V) compound Bi(C6F5)3F2. Keywords: bismuth perfluoroorganic compounds, polar perfluoroorganylations, oxidation with xenon difluoride.Keywords
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