Chiral Phosphoric Acid Diesters as Ligands in Asymmetric Transition Metal Catalyzed Hydrogenation
Open Access
- 1 May 2003
- journal article
- Published by Swiss Chemical Society in Chimia
- Vol. 57 (5) , 290-292
- https://doi.org/10.2533/000942903777679316
Abstract
A chiral phosphoric acid diester, specifically the BINOL-based derivative, has been used for the first time in Rh-, Ir-, and Pd-catalyzed hydrogenation of olefins and imines, giving ee-values of up to 85%.Keywords
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