Calibration of the nitrogen vibron pressure scale for use at high temperatures and pressures

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Abstract
Coherent anti-Stokes Raman scattering (CARS) and spontaneous Raman spectroscopy have been used to obtain vibrational spectra of shock-compressed and static high-pressure fluid nitrogen, respectively. Vibrational frequencies were obtained from the CARS data using a semiclassical model for these spectra. Spontaneous Raman vibrational frequencies were determined by fitting data using a Lorentz-shape line. A functional form was found for the dependence of the vibrational frequency on pressure and temperature to 40 GPa and 5000 K, respectively. By fitting the vibrational data to this form, a pressure scale based on the fluid nitrogen vibron has been calibrated for use at very high temperature. The nitrogen vibron pressure scale was used to determine the fluid-δ nitrogen phase boundary up to 20 GPa and 900 K.