Synthesis of Pinacol Allylic Boronic Esters via Olefin Cross-Metathesis between Pinacol Allylboronate and Terminal or Internal Alkenes

1 January 2002

journal article
letter
Published by Georg Thieme Verlag KG in Synlett

Vol. 2002 (01) , 0128-0130
https://doi.org/10.1055/s-2002-19356

Abstract

The ruthenium-catalyzed olefin cross-metathesis between pinacol allylboronate, CH₂=CHCH₂B(O₂C₂Me₄), and RCH=CH₂ giving RCH=CHCH₂B(O₂C₂Me₄) was carried out in refluxing CH₂Cl₂ in the presence of an alkylidene-ruthenium complex (3 mol%).

Keywords

ALLYLBORON
OLEFIN CROSS-METATHESIS
RUTHENIUM CATALYST

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