First Total Synthesis of 3α,4α-Oxidoagarofuran and (-)-3β,4α-Dihydroxy-β-dihydroagarofuran
- 1 August 1994
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 24 (16) , 2319-2324
- https://doi.org/10.1080/00397919408019057
Abstract
The first stereoselective total synthesis of (–)-3β, 4α-dihydroxy-β-dihydroagarofuran (1) and 3α, 4α-oxidoagarofuran (2) has been described. The key step is the epoxidation of α-agarofuran (6) with dimethyldioxirane.Keywords
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