Catalytic Enantioselective Hydrogenation of Vinyl Bis(boronates)
- 3 November 2004
- journal article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 126 (47) , 15338-15339
- https://doi.org/10.1021/ja044396g
Abstract
Catalytic enantioselective hydrogenation of prochiral vinylmetallic reagents can provide an attractive alternative to hydrometalation and bismetalation of alkenes. In this contribution, the first highly enantioselective hydrogenation of vinyl boronic esters is described. The chiral reduction products are versatile intermediates for chemical synthesis.Keywords
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