Notizen: Isoflavonoid Phytoalexins from Leaves of Trifolium arvense

Abstract
In response to fungal inoculation the leaves of Trifolium arvense accumulate the known isoflavonoid phytoalexins, medicarpin, maackiain, sativan, vestitol, and isovestitol. A previously undescribed isoflavan derivative (arvensan; 7,2′-dimethoxy-4′-hydroxyisoflavan) is also produced by this species. The identification and synthesis of arvensan is described.

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