Scaling behavior at the insulator-metal transition in () where R is a rare-earth element
- 1 November 1992
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 46 (18) , 11813-11825
- https://doi.org/10.1103/physrevb.46.11813
Abstract
We report on the details of the insulator-metal transition (IMT) induced in (,) (R=Y, Gd, Nd) by doping. The resistivity in the insulating regime is analyzed using a generalized hopping approach based on the connectivity criterion. This enables us to estimate the dependence of the localization radius on the Ca concentration independent of dimensionality. Insulating samples with a Y content not too far from the critical concentration =(0.43±0.02) show metallic conduction at high temperature and hopping conduction at low temperature. This shows the coexistence of delocalized and localized states separated by a disorder-induced mobility edge. Ultraviolet-photoemission-spectroscopy (UPS) spectra give evidence for both a shift in the Fermi level to lower energies and the development of new states at the Fermi level. The existence of a mobility edge together with the shift in upon doping shows that the transition is probably of the Anderson type. We present a schematic picture for the density of states in the vicinity of based on the results of spectroscopic and transport data. For this density of states we calculate the electrical resistivity using the Kubo-Greenwood formula. The results are in good qualitative agreement with the experiments. At the IMT the localization radius diverges and the metallic conductivity vanishes following a scaling law σ={1-z/ , with a critical exponent η=1A.
Keywords
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