Photochemical reactions of a silacyclopropene with nitriles leading to new organosilicon ring systems
- 1 January 1978
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 2,p. 80-81
- https://doi.org/10.1039/c39780000080
Abstract
Irradiation of 1,1-dimethyl-2-phenyl-3-trimethylsilylsilacyclopropene (1) in the presence of RCN (R = Ph, Me, and CH2 CHCH2) resulted in the formation of aza-2,8-disilabicyclo[3.2.1]octa-3,6-diene derivatives (2), whereas the photochemical reaction of (1) with acrylonitrile afforded, in addition to (2), another new ring system, 1-aza-2,8-disilabicyclo[3.3.0]octa-3,6-diene (3).Keywords
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