Simplified Matrix Method for Statistical Mechanics of Linear Systems
- 1 September 1968
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 49 (5) , 2294-2300
- https://doi.org/10.1063/1.1670400
Abstract
A matrix method is useful for statistical‐mechanical studies of linear systems of interacting units. For a large class of linear systems, the matrix method presented here leads to matrices whose orders are substantially lower than those obtained by the conventionally used matrix method and thus greatly facilitates mathematical operations. The applications of both the conventional and the simplified methods are illustrated for a DNA molecule; when the molecule has n nucleotide pairs the reduction in the order of the matrix is from to . Next, for a more general type of systems, the order is shown to be reduced from to . Finally, the general steps are outlined for applying the simplified method to any one‐dimensional system of interacting units.
Keywords
This publication has 4 references indexed in Scilit:
- A general treatment of helix-coil equilibria in macromolecular systemsJournal of Molecular Biology, 1966
- Partition Functions of Linear-Chain MoleculesThe Journal of Chemical Physics, 1964
- On the Theory of Helix—Coil Transition in PolypeptidesThe Journal of Chemical Physics, 1961
- Theory of ``Melting'' of the Helical Form in Double Chains of the DNA TypeThe Journal of Chemical Physics, 1960