Reversal of electronic effects between inter- and intra-molecular Michael addition reactions
- 1 January 1982
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 1,p. 36-37
- https://doi.org/10.1039/c39820000036
Abstract
Measurement of the rates of cyclisation of (E)-2-methyl-3-oxo-5-phenylpent-4-en-2-ol and its p-methoxy-derivative in trifluoroacetic acid, together with the rates of the reverse reaction, indicates an influence of stereoelectronic origin which is not present in intermolecular Michael additions.Keywords
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